ACETO ORCEIN MSDS

 

Product Name	RXSOL-60-6507-001
Product Type	ACETO ORCEIN
Revised date	27-04-2019

Company Details:

RX MARINE INTERNATIONAL 105, A wing , BSEL , TECH PARK. VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka

Phone	+91 22 27815541 / 42
Fax	+91 22 2781 1318 :::AOH :0091 9821214367
Email	mail@rxmarine.com

2.1. Substance: ACETO ORCEIN Substance name Contents CAS No Water 50 - 75 7732-18-5 Acetic acid 25 – 50 64-19-7 Orcein 0.01 - 1 1400-62-0 Substance. Contains no other components or impurities which will influence the classification of the product 3.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance: SDS EU 2015: According to Annex II of Regulation (EC) No. 453/2010 (REACH Annex II) Skin corrosion/irritation, H314 Category 1A Full text of classification categories and H statements : see section 16 Adverse physicochemical, human health and environmental effects No additional information available 3.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Symbol(s) : C: Corrosive R Phrase(s):R36/38 Irritating to eyes and skin. S Phrase(s) :S2: Keep out of reach of children. S26: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advise. Hazard pictograms: Signal word: Danger Hazard statements: H314 - Causes severe skin burns and eye damage Precautionary statements: P280 - Wear protective gloves, protective clothing, eye protection, face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a doctor 3.3. Other hazards No additional information available 4.1. Description of first aid measures First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.  5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray. Unsuitable extinguishing media : Do not use extinguishing media containing water. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Use personal protective equipment as required. Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : On land, sweep or shovel into suitable containers. Collect spillage. 6.4. Reference to other sections No additional information available 7.1. Precautions for safe handling Precautions for safe handling : Do not breathe vapours. Avoid contact with skin and eyes. Provide good ventilation in process area to prevent formation of vapour. Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep container tightly closed. 7.3. Specific end use(s) No additional information available 8.1. Control parameters No additional information available 8.2. Exposure controls Hand protection : Protective gloves Eye protection : Chemical goggles or face shield Skin and body protection : Wear suitable protective clothing Respiratory protection : Wear respiratory protection   9.1. Information on basic physical and chemical properties Odour threshold : 1.018 ppm pH : No data available Relative evaporation rate (butylacetate=1) : No data available Melting point : 16.6 °C Freezing point : No data available Boiling point : 100 °C Flash point : 39 °C Auto-ignition temperature : 427 °C Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : 2.3 kPa at 20°C) Relative vapour density at 20 °C : 2.07 Relative density : No data available Density : 1.03 g/cm³ Solubility : Water: Soluble in water Log Pow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : 0.04 - 0.199 vol % 9.2. Other information No additional information available. 10.1. Reactivity Thermal decomposition generates : Corrosive vapours. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No additional information available 10.4. Conditions to avoid Direct sunlight. Overheating. Open flame. Heat. Sparks. 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products Thermal decomposition generates : Corrosive vapours. 11.1. Information on toxicological effects Acute toxicity : Not classified Skin corrosion/irritation : Causes severe skin burns and eye damage. Serious eye damage/irritation : Serious eye damage, category 1, implicit Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified

12.1. Toxicity No additional information available 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil No additional information available 12.5. Results of PBT and vPvB assessment No additional information available 12.6. Other adverse effects No additional information available

13.1. Waste treatment methods General : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations.Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. Special precautions : Handle empty containers with care because residual vapours are flammable.

In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No. (ADR) : 1760 UN-No. (IMDG) : 1760 UN-No.(IATA) : 1760 UN-No.(ADN) : 1760 UN-No. (RID) : 1760 14.2. UN proper shipping name Proper Shipping Name (ADR) : CORROSIVE LIQUID, N.O.S. Proper Shipping Name (IMDG) : CORROSIVE LIQUID, N.O.S. Proper Shipping Name (IATA) : CORROSIVE LIQUID, N.O.S. Proper Shipping Name (ADN) : CORROSIVE LIQUID, N.O.S. Proper Shipping Name (RID) : CORROSIVE LIQUID, N.O.S. Transport document description (ADR) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II, (E) Transport document description (IMDG) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II Transport document description (IATA) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II Transport document description (ADN) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II Transport document description (RID) : UN 1760 CORROSIVE LIQUID, N.O.S., 8, II 14.3. Transport hazard class(es) ADR : Transport hazard class(es) (ADR) : 8 Danger labels (ADR) : 8 IMDG : Transport hazard class(es) (IMDG) : 8 Danger labels (IMDG) : 8 IATA : Transport hazard class(es) (IATA) : 8 Hazard labels (IATA) : 8 AND : Transport hazard class(es) (ADN) : 8 Danger labels (ADN) : 8 RID : Transport hazard class(es) (RID) : 8 Danger labels (RID) : 8 14.4. Packing group Packing group (ADR) : II Packing group (IMDG) : II Packing group (IATA) : II Packing group (ADN) : II Packing group (RID) : II 14.5. Environmental hazards Dangerous for the environment : No Marine pollutant : No Other information : No supplementary information available 14.6. Special precautions for user - Overland transport Classification code (ADR) : C9 Special provision (ADR) : 274 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T11 Portable tank and bulk container special provisions (ADR) : TP2, TP27 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X APP code : B - Transport by sea Special provision (IMDG) : 274 Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T11 Tank special provisions (IMDG) : TP2, TP27 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : B Stowage and handling (IMDG) : SW2 MFAG-No : 154 - Air transport PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L Special provision (IATA) : A3 ERG code (IATA) : 8L - Inland waterway transport Classification code (ADN) : C9 Special provisions (ADN) : 274 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 - Rail transport Classification code (RID) : C9 Special provision (RID) : 274 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T11 Portable tank and bulk container special provisions (RID) : TP2, TP27 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 80 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L Special provision (IATA) : A3 ERG code (IATA) : 8L - Inland waterway transport Classification code (ADN) : C9 Special provisions (ADN) : 274 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 - Rail transport Classification code (RID) : C9 Special provision (RID) : 274 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T11 Portable tank and bulk container special provisions (RID) : TP2, TP27 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 80 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable   15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances. 15.1.2. National regulations Germany AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 <H314>; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product 15.2. Chemical safety assessment No additional information available Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Product:  ACETO ORCEIN